Structural and vibrational behaviour of pyromorphite-vanadinite solid solution series
نویسندگان
چکیده
منابع مشابه
Lead apatites: structural variations among Pb5(BO4)3Cl with B = P (pyromorphite), As (mimetite) and V (vanadinite).
The crystal structure of four Pb apatite samples, Pb5(BO4)3Cl, was refined with synchrotron high-resolution powder X-ray diffraction data, Rietveld refinements, space group P63/m and Z = 2. For this isotypic series, B = P5+ is pyromorphite, B = As5+ is mimetite and B = V5+ is vanadinite. The ionic radius for As5+ (0.355 Å) is similar to that of V5+ (0.335 Å), and this is twice as large as that ...
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Orpiment, getchellite and stibnite from Zarshuran deposit, NW Iran, exhibit extensive As-Sb substitution. There are four known minerals along As2S3-Sb2S3 join, i.e. orpiment (As2S3), Wakabayashilite [(As,Sb)20S30], getchellite (AsSbS3) and stibnite (Sb2S3). Extensive mineralogical studies by scanning electron microscope (SEM) and electron probe micro-analyzer (EPMA) indicate that getchellite fr...
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15 صفحه اولStructural Behaviour of Solid Solutions in the NdAlO3-SrTiO3 System
Single-phase mixed aluminates-titanates Nd1-x Sr x Al1-x Ti x O3 (x = 0.3 ÷ 0.9) were prepared from stoichiometric amounts of constituent oxides Nd2O3, Al2O3, TiO2 and strontium carbonate SrCO3 by solid-state reaction technique in air at 1773 K. Crystal structure parameters of Nd1-x Sr x Al1-x Ti x O3 were refined by full-profile Rietveld refinement in space groups R [Formula: see text] c (x = ...
متن کاملsolid solution in the as2s3-sb2s3 series at
orpiment, getchellite and stibnite from zarshuran deposit, nw iran, exhibit extensive as-sb substitution. there are four known minerals along as2s3-sb2s3 join, i.e. orpiment (as2s3), wakabayashilite [(as,sb)20s30], getchellite (assbs3) and stibnite (sb2s3). extensive mineralogical studies by scanning electron microscope (sem) and electron probe micro-analyzer (epma) indicate that getchellite fr...
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ژورنال
عنوان ژورنال: Geology, Geophysics & Environment
سال: 2015
ISSN: 0138-0974
DOI: 10.7494/geol.2015.41.1.135